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Thieme Chemistry Journal Awardees - Where are They Now? Synthesis of the Marine Glycolipid Dioctadecanoyl Discoside

Miller

Authors



Abstract

The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with ß-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside, its peracetate and the unnatural ß-derivatives.

Acceptance Date Oct 21, 2009
Publication Date Dec 1, 2009
Journal Synlett
Print ISSN 0936-5214
Publisher Thieme Gruppe
Pages 3099 -3102
DOI https://doi.org/10.1055/s-0029-1218301
Keywords marine sponge, glycolipid, mannose, glycosylation, inositol
Publisher URL http://dx.doi.org/10.1055/s-0029-1218301