Rich, M and Mendecki, L and Mensah, ST and Blanco-Martinez, E and Armas, S and Calvo-Marzal, P and Radu, A and Chumbimuni-Torres, KY (2016) Circumventing Traditional Conditioning Protocols in Polymer Membrane-Based Ion-Selective Electrodes. Analytical Chemistry, 88 (17). 8404 - 8408. ISSN 1520-6882

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Abstract

Preparation of ion-selective electrodes (ISEs) often requires long and complicated conditioning protocols limiting their application as tools for in-field measurements. Herein, we eliminated the need for electrode conditioning by loading the membrane cocktail directly with primary ion solution. This proof of concept experiment was performed with iodide, silver, and sodium selective electrodes. The proposed methodology significantly shortened the preparation time of ISEs, yielding functional electrodes with submicromolar detection limits. Moreover, it is anticipated that this approach may form the basis for the development of miniaturized all-solid-state ion-selective electrodes for in situ measurements.

Item Type: Article
Additional Information: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via ACS Publications at http://dx.doi.org/10.1021/acs.analchem.6b01542 - please refer to any applicable terms of use of the publisher.
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Physical and Geographical Sciences
Related URLs:
Depositing User: Symplectic
Date Deposited: 13 Dec 2016 09:51
Last Modified: 15 Aug 2017 01:30
URI: http://eprints.keele.ac.uk/id/eprint/2646

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