McCarney, EP, Hawes, CS ORCID: 0000-0001-6902-7939, Kitchen, JA, Byrne, K, Schmitt, W and Gunnlaugsson, T (2018) A Lanthanide Luminescent Cation Exchange Material Derived from a Flexible Tricarboxylic Acid 2,6-Bis(1,2,3-triazol-4-yl)pyridine (btp) Tecton. Inorganic Chemistry, 57 (7). pp. 3920-3930. ISSN 0020-1669

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Abstract

The synthesis of the three-dimensional metal–organic framework material, [Zn7L6]·(H2NMe2)4·(H2O)45 (1), derived from a flexible tricarboxylic acid 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligand, is presented. The btp ligand, H3L, adopts a three-dimensional hydrogen bonding network in the crystalline state through a combination of carboxylic acid dimer and syn–anti-btp/carboxylic acid hydrogen bonding synthons. The Zn(II) species 1 exhibits a three-dimensional framework structure with the rare crs topology and contains linear and undulated solvent channels extending in three dimensions. The guest exchange and gas adsorption properties of 1 were investigated; herein we demonstrate the exchange of dimethylammonium cations from the as-synthesized material with cationic guest molecules in the form of dyes and luminescent Ln(III) ions. Sensitization of Eu(III) and Tb(III) inside the porous network of 1 was achieved upon cation exchange, with a view toward developing functional luminescent materials.

Item Type: Article
Uncontrolled Keywords: physical and theoretical chemistry, inorganic chemistry
Subjects: Q Science > QD Chemistry
Depositing User: Symplectic
Date Deposited: 09 Mar 2018 13:17
Last Modified: 04 Jul 2018 13:36
URI: http://eprints.keele.ac.uk/id/eprint/4539

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