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Li, N, Matthews, PD ORCID: https://orcid.org/0000-0002-1362-8003, Luo, H-K and Wright, DS (2016) Novel properties and potential applications of functional ligand-modified polyoxotitanate cages. Chemical Communications, 52 (75). pp. 11180-11190.

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Abstract

Functional ligand-modified polyoxotitanate (L-POT) cages of the general type [TixOy(OR)z(L)m] (OR = alkoxide, L = functional ligand) can be regarded as molecular fragments of surface-sensitized solid-state TiO2, and are of value as models for studying the interfacial charge and energy transfer between the bound functional ligands and a bulk semiconductor surface. These L-POTs have also had a marked impact in many other research fields, such as single-source precursors for TiO2 deposition, inorganic–organic hybrid material construction, photocatalysis, photoluminescence, asymmetric catalysis and gas adsorption. Their atomically well-defined structures provide the basis for the understanding of structure/property relationships and ultimately for the rational design of new cages targeting specific uses. This highlight focuses on recent advances in L-POTs research, with emphasis on their novel properties and potential applications.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 13 Apr 2018 15:05
Last Modified: 11 Apr 2019 09:25
URI: http://eprints.keele.ac.uk/id/eprint/4751

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