Marshall, WG, Jones, RH and Knight, KS (2018) Negative 2D thermal expansion in the halogen bonded acetone bromine complex. CrystEngComm, 20 (23). pp. 3246-3250. ISSN 1466-8033

[img] Text
R Jones - Negative 2D thermal expansion in the halogen bonded acetone bromine complex.pdf - Accepted Version
Restricted to Repository staff only until 4 May 2019.
Available under License Creative Commons Attribution Non-commercial.

Download (613kB)

Abstract

The crystal structure of the complex formed between acetone and bromine has been determined between 14 K and 200 K. The structure exhibits negative 2D thermal expansion at low temperature and colossal thermal expansion in the perpendicular dimension. At low temperature the C[double bond{,} length as m-dash]O bond is significantly longer than that observed in free acetone.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 09 May 2018 08:12
Last Modified: 13 Jun 2018 08:11
URI: http://eprints.keele.ac.uk/id/eprint/4872

Actions (login required)

View Item View Item