Engstrom, JR, Savyasachi, AJ, Parhizkar, M, Sutti, A, Hawes, CS ORCID: 0000-0001-6902-7939, White, J, Gunnlaugsson, T and Pfeffer, FM (2018) Norbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs). Chemical Science. ISSN 2041-6520

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Abstract

Phenylalanine functionalised norbornene (9:Na) functions as a potent, low molecular-mass (MW = 333 Da) ionic organogelator with a minimum gelating concentration of 0.5 wt% in THF, i-PrOH, 1,4-dioxane and n-BuOH. Fibrous crystals form in the gel and X-ray crystallography identified a cation mediated helical assembly process controlled by the chirality of the phenylalanine. In additon to excellent gelating properties 9:Na readily forms aqueous biphasic and triphasic systems.

Item Type: Article
Additional Information: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at http://doi.org/10.1039/C8SC01798K - please refer to any applicable terms of use of the publisher.
Subjects: Q Science > QD Chemistry
Depositing User: Symplectic
Date Deposited: 17 May 2018 09:16
Last Modified: 04 Jul 2018 13:34
URI: http://eprints.keele.ac.uk/id/eprint/4911

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