Summerton, E, Hollamby, M, Zimbitas, G, Snow, T, Smith, A, Sommertune, J, Bettiol, J, Jones, C, Britton, M and Bakalis, S (2018) The impact of N,N-dimethyldodecylamine N-oxide (DDAO) concentration on the crystallisation of sodium dodecyl sulfate (SDS) systems and the resulting changes to viscosity, crystal structure, shape and the kinetics of crystal growth. Journal of Colloid and Interface Science.

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Abstract

Hypothesis
At low temperatures stability issues arise in commercial detergent products when surfactant crystallisation occurs, a process which is not currently well-understood. An understanding of the phase transition can be obtained using a simple binary SDS (sodium dodecyl sulfate) + DDAO (N,N-dimethyldodecylamine N-oxide) aqueous system. It expected that the crystallisation temperature of an SDS system can be lowered with addition of DDAO, thus providing a route to improve detergent stability.

Experiments
Detergent systems are typically comprised of anionic surfactants, non-ionic surfactants and water. This study explores the crystallisation of a three component system consisting of sodium dodecyl sulfate (SDS), N,N–dimethyldodecylamine N-oxide (DDAO), and water using wide-angle X-ray scattering (WAXS), differential scanning calorimetry (DSC) and confocal Raman microscopy.

Findings
The presence of DDAO lowered the crystallisation temperature of a 20 wt% SDS system. For all aqueous mixtures of SDS + DDAO at low temperatures, SDS hydrated crystals, SDS.1/2H2O or SDS·H2O, formed. SDS hydrates comprising of layers of SDS separated by water layers. DDAO tended to reside in the vicinity of these SDS crystals. In the absence of DDAO an additional intermediary hydrate structure, SDS.1/8H2O, formed whereas for mixed SDS + DDAO systems no such structure was detected during crystallisation.

Item Type: Article
Additional Information: The final published version can be accessed online at: https://www.sciencedirect.com/science/article/pii/S0021979718305794
Uncontrolled Keywords: sodium dodecyl sulfate; N,N-dimethyldodecylamine N-oxide; low temperature; crystallization; X-ray scattering; detergent stability
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 21 May 2018 11:18
Last Modified: 19 May 2019 01:30
URI: http://eprints.keele.ac.uk/id/eprint/4926

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