Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands

Nodzewska, Aneta; Wadolowska, Agnieszka; Watkinson, Mike

doi:10.1016/j.ccr.2018.12.004

Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands

Nodzewska, Aneta; Wadolowska, Agnieszka; Watkinson, Mike

Authors

Aneta Nodzewska

Agnieszka Wadolowska

Mike Watkinson

Abstract

In recent years, many supported manganese catalysts for the oxidative transformations of hydrocarbons by various terminal oxidants have been designed and tested. A vast range of inorganic (e.g. silica, carbon, zeolites), organic (e.g. polymers, dendrimers), and hybrid (e.g. polymeric phosphates, metal-organic frameworks) materials have been chosen to immobilise catalysts using various anchoring and embedding methods including covalent bonding, axial coordination and non-covalent interactions. This review provides a comprehensive overview of the applications of heterogenised manganese complexes with different nitrogen containing ligands, including porphyrins, salens and amines immobilized on inorganic or/and organic supports in the catalytic oxidation of alkanes and alkenes.

Journal Article Type	Article
Acceptance Date	Dec 11, 2018
Online Publication Date	Jan 4, 2019
Publication Date	Mar 1, 2019
Publicly Available Date	May 26, 2023
Journal	Coordination Chemistry Reviews
Print ISSN	0010-8545
Publisher	Elsevier
Volume	382
Pages	181-216
DOI	https://doi.org/10.1016/j.ccr.2018.12.004
Keywords	alkene; alkane; manganese; ligands
Publisher URL	https://doi.org/10.1016/j.ccr.2018.12.004