Babu, SS and Hollamby, MJ and Aimi, J and Ozawa, H and Saeki, A and Seki, S and Kobayashi, K and Hagiwara, K and Yoshizawa, M and Möhwald, H and Nakanishi, T (2013) Nonvolatile liquid anthracenes for facile full-colour luminescence tuning at single blue-light excitation. Nature Communications, 4 (1969). ISSN 2041-1723

Nonvolatile liquid anthracenes for facile full-colour luminescence tuning at single blue-light excitation..pdf

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Nonvolatile room-temperature luminescent molecular liquids are a new generation of organic soft materials. They possess high stability, versatile optical properties, solvent-free fluid behaviour and can effectively accommodate dopant dye molecules. Here we introduce an approach to optimize anthracene-based liquid materials, focussing on enhanced stability, fluorescence quantum yield, colour tunability and processability, with a view to flexible electronic applications. Enveloping the anthracene core in low-viscosity branched aliphatic chains results in stable, nonvolatile, emissive liquid materials. Up to 96% efficient energy-transfer-assisted tunable emission is achieved by doping a minute amount of acceptor dye in the solvent-free state. Furthermore, we use a thermoresponsive dopant to impart thermally controllable luminescence colours. The introduced strategy leading to diverse luminescence colours at a single blue-light excitation can be an innovative replacement for currently used luminescent materials, providing useful continuous emissive layers in developing foldable devices.

Item Type: Article
Uncontrolled Keywords: chemical sciences; materials science; organic chemistry; physical chemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Physical and Geographical Sciences
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Depositing User: Symplectic
Date Deposited: 22 Jun 2015 14:45
Last Modified: 23 May 2016 11:09

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