Al-Ani, A, Mordvinova, N, Lebedev, O, Khodakov, A and Zholobenko, VL ORCID: https://orcid.org/0000-0002-6024-0503 (2019) Ion-exchanged Zeolite P as a Nanostructured Catalyst for Biodiesel Production. Energy Reports, 5. 357 -363.

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Abstract

Nano-crystalline synthetic gismondine modified via cation exchange has been utilised as a highly active and selective catalyst for the production of biofuel. In comparison with low silica zeolites FAU and LTA, K-form of gismondine, based on the maximum aluminium P (MAP) zeolite, exhibited a significant improvement in catalytic performance in the methanolysis of bio-oil, which can be attributed to its nano-particle morphology and high basicity associated with the high Al content and high degree of ion exchange, as demonstrated by the TEM, XRD, TGA, NMR, XPS and CO2-TPD studies. To the best of our knowledge, this is the first report on a successful catalytic application of basic K-MAP zeolite.

Item Type: Article
Additional Information: © 2019 The Authors. Published by Elsevier Ltd.
Uncontrolled Keywords: Synthetic gismondine; Zeolites; Transesterification; Basic sites; Nanostructured catalysts
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 13 Mar 2019 15:44
Last Modified: 11 Jun 2019 15:14
URI: http://eprints.keele.ac.uk/id/eprint/6053

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