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Indium(III) promoted oxidative P-P coupling of silylphosphines

Cartlidge, Ashleigh J.

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Authors

Ashleigh J. Cartlidge



Abstract

The reaction of indium(III) salts with Ph2PSiMe3 and PhP(SiMe3)2 gives rise to a one- and two-electron reductive P-P coupling respectively, with the formation of new P-P bonds resulting in the preparation of (Ph2P)2 and the cyclicoligophosphane compounds (PhP)4 and (PhP)6.

Journal Article Type Article
Acceptance Date Dec 19, 2021
Online Publication Date Dec 23, 2021
Publication Date Apr 1, 2022
Publicly Available Date Mar 28, 2024
Journal Inorganica Chimica Acta
Print ISSN 0020-1693
Publisher Elsevier
Pages 120772 - 120772
DOI https://doi.org/10.1016/j.ica.2021.120772
Keywords P-P bond formation; Redox coupling; Silylphosphines; Indium(III) reduction; Phosphorus oxidative coupling
Publisher URL https://doi.org/10.1016/j.ica.2021.120772

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