Gavin Miller g.j.miller@keele.ac.uk
Adaptable Synthesis of C-Glycosidic Multivalent Carbohydrates and Succinamide-Linked Derivatization
Miller
Authors
Abstract
A modular approach to the synthesis of trivalent C-glycosidic carbohydrates is described. The approach is illustrated employing carboxylate-terminated C-glycosidic d-mannose, d-glucose, and d-galactose derivatives with different length C1-linked spacer units and also core units with different length linker units attached. The central core scaffold is additionally functionalized via a succinamide-based, conjugatable linker unit, exemplified in an extended multivalent derivative [31] and a pyrene-bearing fluorsecent-labeled tris-C-mannosyl conjugate [33].
| Publication Date | Nov 19, 2010 |
|---|---|
| Journal | Organic Letters |
| Print ISSN | 1523-7060 |
| Publisher | American Chemical Society |
| Pages | 5262 - 5265 |
| DOI | https://doi.org/10.1021/ol102310x |
| Publisher URL | https://doi.org/10.1021/ol102310x |
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