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Engstrom, JR, Savyasachi, AJ, Parhizkar, M, Sutti, A, Hawes, CS ORCID: https://orcid.org/0000-0001-6902-7939, White, J, Gunnlaugsson, T and Pfeffer, FM
(2018)
Norbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs).
Chemical Science.
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c8sc01798k.pdf - Accepted Version Available under License Creative Commons Attribution. Download (2MB) | Preview |
Abstract
Phenylalanine functionalised norbornene (9:Na) functions as a potent, low molecular-mass (MW = 333 Da) ionic organogelator with a minimum gelating concentration of 0.5 wt% in THF, i-PrOH, 1,4-dioxane and n-BuOH. Fibrous crystals form in the gel and X-ray crystallography identified a cation mediated helical assembly process controlled by the chirality of the phenylalanine. In additon to excellent gelating properties 9:Na readily forms aqueous biphasic and triphasic systems.
Item Type: | Article |
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Additional Information: | This is the accepted author manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at http://doi.org/10.1039/C8SC01798K - please refer to any applicable terms of use of the publisher. |
Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Natural Sciences > School of Chemical and Physical Sciences |
Depositing User: | Symplectic |
Date Deposited: | 17 May 2018 09:16 |
Last Modified: | 24 May 2019 14:27 |
URI: | https://eprints.keele.ac.uk/id/eprint/4911 |
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