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Barry, DE, Hawes, CS ORCID: https://orcid.org/0000-0001-6902-7939, Byrne, JP, Poulsen, BLC, Ruether, M, O Brien, JE and Gunnlaugsson, T
(2017)
A folded [2 x 2] metallo-supramolecular grid from a bis-tridentate (1,2,3-triazol-4-yl)-picolinamide (tzpa) ligand.
Dalton Transactions, 46 (19).
6464 -6472.
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Manuscript_No Markup.docx - Accepted Version Download (4MB) |
Abstract
A flexible ditopic ligand 1 containing two N,N,O-tridentate (1,2,3-triazol-4-yl)-picolinamide chelating pockets is reported and the formation of multimetallic architectures is explored in the solid and the solution phase. The self-assembled ZnII complex [Zn4(1)4](ClO4)8 exhibited a folded [2 × 2] square grid supramolecular architecture that selectively assembled in MeCN solution as shown using various spectroscopic techniques. The closely related FeII complex shows equivalent behaviour in the solid state, while a discrete dinuclear species [Cu2(NO3)41]·5MeCN was the sole product observed in the solid state from the reaction between 1 and CuII under similar conditions.
Item Type: | Article |
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Additional Information: | This is the accepted author manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at http://dx.doi.org/10.1039/C7DT01533J - please refer to any applicable terms of use of the publisher. |
Subjects: | Q Science > QD Chemistry |
Divisions: | Faculty of Natural Sciences > School of Chemical and Physical Sciences |
Depositing User: | Symplectic |
Date Deposited: | 29 May 2018 15:50 |
Last Modified: | 04 Jul 2018 13:36 |
URI: | https://eprints.keele.ac.uk/id/eprint/4954 |
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