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Watkinson, M ORCID: https://orcid.org/0000-0003-1877-5667, Nodzewska, A and Wadolowska, A (2019) Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands. Coordination Chemistry Reviews, 382. pp. 181-216.

Text AW_Revised manuscript-20-12-18.docx - Accepted Version Available under License Creative Commons Attribution Non-commercial No Derivatives. Download (2MB)

Abstract

In recent years, many supported manganese catalysts for the oxidative transformations of hydrocarbons by various terminal oxidants have been designed and tested. A vast range of inorganic (e.g. silica, carbon, zeolites), organic (e.g. polymers, dendrimers), and hybrid (e.g. polymeric phosphates, metal-organic frameworks) materials have been chosen to immobilise catalysts using various anchoring and embedding methods including covalent bonding, axial coordination and non-covalent interactions. This review provides a comprehensive overview of the applications of heterogenised manganese complexes with different nitrogen containing ligands, including porphyrins, salens and amines immobilized on inorganic or/and organic supports in the catalytic oxidation of alkanes and alkenes.

Item Type:	Article
Additional Information:	This is the final published version of the article (version of record). It first appeared online via Elsevier at https://doi.org/10.1016/j.ccr.2018.12.004 - Please refer to any applicable terms of use of the publisher.
Uncontrolled Keywords:	alkene; alkane; manganese; ligands
Subjects:	Q Science > QD Chemistry
Divisions:	Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User:	Symplectic
Date Deposited:	11 Jan 2019 09:23
Last Modified:	04 Jan 2020 01:30
URI:	https://eprints.keele.ac.uk/id/eprint/5666

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