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Cartlidge, AJ and Matthews, PD (2022) Indium(III) Promoted Oxidative P-P Coupling of Silylphosphines. Inorganica Chimica Acta, 533 (120772). 120772 - 120772. ISSN 0020-1693

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Abstract

The reaction of indium(III) salts with Ph2PSiMe3 and PhP(SiMe3)2 gives rise to a one- and two-electron reductive P-P coupling respectively, with the formation of new P-P bonds resulting in the preparation of (Ph2P)2 and the cyclicoligophosphane compounds (PhP)4 and (PhP)6.

Item Type: Article
Additional Information: The final version of this article and all relevant information related to it, including copyrights, can be found on the publisher website at; https://www.sciencedirect.com/science/article/pii/S0020169321005284?via%3Dihub
Uncontrolled Keywords: P-P bond formation; Redox coupling; Silylphosphines; Indium(III) reduction; Phosphorus oxidative coupling
Subjects: Q Science > QD Chemistry
Q Science > QD Chemistry > QD415 Biochemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 06 Jan 2022 14:49
Last Modified: 10 Jun 2022 08:40
URI: https://eprints.keele.ac.uk/id/eprint/10463

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