Ashleigh J. Cartlidge
Indium(III) promoted oxidative P-P coupling of silylphosphines
Cartlidge, Ashleigh J.
Authors
Abstract
The reaction of indium(III) salts with Ph2PSiMe3 and PhP(SiMe3)2 gives rise to a one- and two-electron reductive P-P coupling respectively, with the formation of new P-P bonds resulting in the preparation of (Ph2P)2 and the cyclicoligophosphane compounds (PhP)4 and (PhP)6.
Journal Article Type | Article |
---|---|
Acceptance Date | Dec 19, 2021 |
Online Publication Date | Dec 23, 2021 |
Publication Date | Apr 1, 2022 |
Publicly Available Date | Mar 29, 2024 |
Journal | Inorganica Chimica Acta |
Print ISSN | 0020-1693 |
Publisher | Elsevier |
Pages | 120772 - 120772 |
DOI | https://doi.org/10.1016/j.ica.2021.120772 |
Keywords | P-P bond formation; Redox coupling; Silylphosphines; Indium(III) reduction; Phosphorus oxidative coupling |
Publisher URL | https://doi.org/10.1016/j.ica.2021.120772 |
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https://creativecommons.org/licenses/by-nc-nd/4.0/
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