Florence, GJ, Aslam, T, Miller, GJ, Milne, GDS and Conway, SJ (2009) Thieme Chemistry Journal Awardees - Where are They Now? Synthesis of the Marine Glycolipid Dioctadecanoyl Discoside. Synlett, 19. 3099 -3102. ISSN 1437-2096

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The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with β-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside, its peracetate and the unnatural β-derivatives.

Item Type: Article
Uncontrolled Keywords: marine sponge, glycolipid, mannose, glycosylation, inositol
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Physical and Geographical Sciences
Related URLs:
Depositing User: Symplectic
Date Deposited: 26 Nov 2015 09:30
Last Modified: 08 Jul 2019 11:51
URI: https://eprints.keele.ac.uk/id/eprint/1232

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