Transalkylation of Toluene with 1,2,4-Trimethylbenzene over Large Pore Zeolites

Chansai, S; Garforth, AA; Zholobenko, V; Almulla, FM; Hill, PI

doi:10.1021/acs.iecr.7b01388

Transalkylation of Toluene with 1,2,4-Trimethylbenzene over Large Pore Zeolites

Chansai, S; Garforth, AA; Zholobenko, V; Almulla, FM; Hill, PI

Authors

S Chansai

AA Garforth

V Zholobenko

FM Almulla

PI Hill

Abstract

Using industrially relevant operating parameters, the transalkylation of 1,2,4-trimethylbenzene (TMB) with toluene was studied. The effect of acidity and structure, increased reaction pressure, and very low levels of Pt impregnation have been investigated over both H-form and Pt-loaded zeolites: Beta, MOR, and Y. A fixed bed reactor was used at WHSV of 5 h–1, 400 °C, and a 50:50 wt % toluene:TMB ratio with the order of activity after 50 h TOS of Y > Beta » MOR at 1 bar. At elevated pressure (10 bar), all catalysts showed better performance with significant improvement in MOR as pore blockage reduced and the order of activity was Beta > MOR > Y. Incorporation of Pt (0.08 wt %) further improved the activity of all catalysts with the highest conversion after 50 h TOS over Beta (62 wt %) where Beta and MOR yielded similar levels of xylenes (40 wt %). All catalysts were further optimized for activity while maintaining the desired stability and highest xylenes yield.

Acceptance Date	Aug 18, 2017
Publication Date	Aug 18, 2017
Journal	Industrial & Engineering Chemistry Research
Print ISSN	0888-5885
Publisher	American Chemical Society
Pages	9799 -9808
DOI	https://doi.org/10.1021/acs.iecr.7b01388
Keywords	Transalkylation, toluene, 1,2,4-trimethylbenzene, Beta, Y, Mordenite, ZSM-5
Publisher URL	http://dx.doi.org/10.1021/acs.iecr.7b01388