Peter Matthews p.d.matthews@keele.ac.uk
Novel xanthate complexes for the size-controlled synthesis of copper sulfide nanorods
Matthews, P; Deogratius, G; McNaughter, PD; Rafery, J; O'Brien, P; Vitorica-Yrezabal, I; Mubofu, EB; Al-Shakban, M
Authors
G Deogratius
PD McNaughter
J Rafery
P O'Brien
I Vitorica-Yrezabal
EB Mubofu
M Al-Shakban
Abstract
We present a simple, easily scalable route to monodisperse copper sulfide nanocrystals by the hot injection of a series of novel copper(I) xanthate single-source precursors [(PPh3)2Cu(S2COR)] (R = isobutyl, 2-methoxyethyl, 2-ethoxyethyl, 1-methoxy-2-propyl, 3-methoxy-1-butyl, and 3-methoxy-3-methyl-1-butyl), whose crystal structures are also reported. We show that the width of the obtained rods is dependent on the length of the xanthate chain, which we rationalize through a computational study, where we show that there is a relationship between the ground-state energy of the precursor and the copper sulfide rod width.
Acceptance Date | May 22, 2017 |
---|---|
Publication Date | Jul 19, 2017 |
Publicly Available Date | Mar 29, 2024 |
Journal | Inorganic Chemistry |
Print ISSN | 0020-1669 |
Publisher | American Chemical Society |
Pages | 9247-9254 |
DOI | https://doi.org/10.1021/acs.inorgchem.7b01288 |
Publisher URL | https://pubs.acs.org/doi/10.1021/acs.inorgchem.7b01288 |
Files
manuscript - final.docx
(1.5 Mb)
Document
Publisher Licence URL
https://creativecommons.org/licenses/by-nc/4.0/
You might also like
Colloidal III-V quantum dots: a synthetic perspective
(2023)
Journal Article
55 Cancri e's occultation captured with CHEOPS
(2023)
Journal Article
Reeling them in: Ph2PSiMe3 in the sequential formation of InP magic-sized clusters
(2022)
Journal Article
Chemical Vapor Deposition of Tin Sulfide from Diorganotin(IV) Dixanthates
(2018)
Journal Article
Downloadable Citations
About Keele Repository
Administrator e-mail: research.openaccess@keele.ac.uk
This application uses the following open-source libraries:
SheetJS Community Edition
Apache License Version 2.0 (http://www.apache.org/licenses/)
PDF.js
Apache License Version 2.0 (http://www.apache.org/licenses/)
Font Awesome
SIL OFL 1.1 (http://scripts.sil.org/OFL)
MIT License (http://opensource.org/licenses/mit-license.html)
CC BY 3.0 ( http://creativecommons.org/licenses/by/3.0/)
Powered by Worktribe © 2024
Advanced Search