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Keyzer, EN, Matthews, PD, Liu, Z, Bond, AD, Grey, CP and Wright, DS (2017) Synthesis of Ca(PF6)2, formed via nitrosonium oxidation of calcium. Chemical Communications, 53 (33). pp. 4573-4576. ISSN 1359-7345

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Abstract

The development of rechargeable Ca-ion batteries as an alternative to Li systems has been limited by the availability of suitable electrolyte salts. We present the synthesis of complexes of Ca(PF6)2 (a key potential Ca battery electrolyte salt) via the treatment of Ca metal with NOPF6, and explore their conversion to species containing PO2F2− under the reaction conditions.

Item Type: Article
Additional Information: The final published version of the article can be found online at http://pubs.rsc.org/en/Content/ArticleLanding/2017/CC/C7CC01938F#!divAbstract
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 04 Apr 2018 12:13
Last Modified: 26 Mar 2019 15:51
URI: https://eprints.keele.ac.uk/id/eprint/4709

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