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Marshall, WG, Jones, RH and Knight, KS (2018) Negative 2D thermal expansion in the halogen bonded acetone bromine complex. CrystEngComm, 20 (23). pp. 3246-3250. ISSN 1466-8033

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Abstract

The crystal structure of the complex formed between acetone and bromine has been determined between 14 K and 200 K. The structure exhibits negative 2D thermal expansion at low temperature and colossal thermal expansion in the perpendicular dimension. At low temperature the C[double bond{,} length as m-dash]O bond is significantly longer than that observed in free acetone.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 09 May 2018 08:12
Last Modified: 04 May 2019 01:30
URI: https://eprints.keele.ac.uk/id/eprint/4872

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