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Nodzewska, A and Watkinson, M (2018) Remarkable increase in the rate of the catalytic epoxidation of electron deficient styrenes through the addition of Sc(OTf)3 to the MnTMTACN catalyst. Chemical Communications, 54 (12). 1461 -1464. ISSN 1364-548X

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Abstract

The effect of Lewis acids on the catalytic activity of [Mn2(μ-O)3(TMTACN)2](PF6)2 in the epoxidation of styrenes using hydrogen peroxide as the oxidant has shown that the addition of Sc(OTf)3 at low catalytic loading results in a very significant increase in the efficiency of the catalyst and a reduction of the reaction time to only 3 minutes in most cases.

Item Type: Article
Additional Information: This is the accepted author manuscript (AAM). The final published version (version of record) is available online via Royal Society of Chemistry at http://doi.org/10.1039/C7CC09698D - please refer to any applicable terms of use of the publisher.
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Related URLs:
Depositing User: Symplectic
Date Deposited: 03 Jun 2019 14:46
Last Modified: 03 Jun 2019 14:48
URI: https://eprints.keele.ac.uk/id/eprint/6435

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