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Ahmadipour, S and Miller, GJ (2019) 6R/S-deutero-α-d-mannopyranoside 1-phosphate. Molbank, 2019 (3). M1068 - M1068. ISSN 1422-8599

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Abstract

6R/S-deutero-α-d-mannopyranoside 1-phosphate was synthesised from a C6 aldehydic mannose thioglycoside donor in four steps. Using NaBD4 as the reductant, isotopic enrichment at C6 was achieved and the resultant C6-deuterated material was converted through to the glycosyl 1-phosphate using a protection/glycosylation/deprotection sequence. The product was fully characterised by 1H, 13C, 31P and 2D NMR, alongside MS analysis.

Item Type: Article
Additional Information: This is the final published version of the article (version of record). It first appeared online via MDPI AG at https://doi.org/10.3390/M1068 - please refer to any applicable terms of use of the publisher.
Uncontrolled Keywords: mannose; glycosyl-phosphate; deuterium; isotope; NMR
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Natural Sciences > School of Chemical and Physical Sciences
Depositing User: Symplectic
Date Deposited: 10 Oct 2019 10:26
Last Modified: 25 Mar 2021 10:39
URI: https://eprints.keele.ac.uk/id/eprint/7005

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